Synthesis, structure, immobilization and solid-state NMR of new dppp- and tripod-type chelate linkers
نویسندگان
چکیده
Chelating phosphines incorporating ethoxysilane functions for immobilizations have been synthesized and fully characterized. (EtO)Si(CH2PPh2)3, (EtO)2Si(CH2PPh2)2, and Si(CH2PPh2)4 could be prepared in high yields from cheap starting materials. The ethoxysilanes, as well as a Pd complex thereof have been characterized by X-ray structures, and immobilized on silica. The success of the immobilization was proved by P solid-state NMR of the dry materials and of the suspensions. Two representative chelate metal complexes, (EtO)2Si(CH2PPh2)2PdCl2 and (EtO)Si(CH2PPh2)3W(CO)3 have been synthesized, characterized and immobilized. 2005 Elsevier B.V. All rights reserved.
منابع مشابه
Easy one-pot synthesis of new dppm-type linkers for immobilizations.
New synthetic routes to symmetric and unsymmetric dppm-type chelate linkers containing the ethoxysilane group are described and the compounds were characterized also by solid-state NMR spectroscopy and X-ray structures.
متن کاملSynthesis, Immobilization, MAS and HR-MAS NMR of a New Chelate Phosphine Linker System, and Catalysis by Rhodium Adducts Thereof
A new class of tridentate phosphine ligands with the general formula [MePACHTUNGTRENNUNG{(CH2)xPPh2}3] I (x=4, 7, 11) and [MePACHTUNGTRENNUNG(CH2PPh2)3] OTf , has been synthesized and fully characterized. The linkers have been immobilized on silica with their phosphonium moieties via electrostatic interactions, and their mobility and leaching has been studied by solid-state HR-MAS (high-resolut...
متن کاملSynthesis and Crystal Structure of Cobalt(III) Complexes of Salen Type Schiff Bases and Tertiary Phosphanes as Ligands
The new [Co(Salen)(PBu3)2]ClO4, [Co(Salen)(PBu3)2]BF4, [Co(Salpn)(PBu3)2]ClO4 and [Co(Salen)(PMe2Ph)2]ClO4 ( where salen = bis(salisylaldehyde)ethylenediimine)) complexes were synthesiszed and chracterized by IR, UV-Vis, 1H NMR spectroscopy and elemental analysis. The IR and 1H NMR spectra cofirmed that the synthesised complexes contain Schiff base ligand, phosphane and conter ion and the eleme...
متن کاملSynthesis of Binuclear Monohydroxo Bridged Copper(II) Complexes with 1,10-Phenanthroline and 4,4'-Dimethyl-2,2'-Bipyridine
Tow new compound of type [(chelate)2Cu-OH-Cu(chelate)2] X3.nH2O, where chelate=1,10-phenanthroline; X=Cl¯(n=3.5) and chelate=4,4'-dimethyl-2,2'-bipyridine; (n=5) have been synthesized and their properties investigated. The complexes show room temperature magnetic moment order of 1.0 B.M. per copper atom. The X-band ESR spectrum of powdered sample...
متن کاملSynthesis and Characterization of New Mercury (II) Complexes with Bidentate Chelating Schiff Base Iminopyridine Ligand
First, Schiff base iminopyridine ligands has been prepared by the condensation between primaryamines, different substituted anilines and active carbonyl group of pyridine carboxaldehyde, thenthe complexes [diiodo (3-ethylphenyl) pyridine-2-yl methylene amine] mercury(II), complex a,[dibromo (2,5-dimethylphenyl) pyridine-2-yl methylene amine] mercury(II) complex b, and[dinitrato bis-(2,6-dimethy...
متن کامل